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• W2003237289 abstract "Reaction of Fe3(CO)12 with 1,8-bis(diphenylphosphino)naphthalene (dppn) yields the tetranuclear oxide cluster [Fe4(CO)10(μ4-O)(κ2-dppn)] (1), which has been crystallographically characterized. It is a member of the [M4(CO)12(μ4-E)]n− series of butterfly clusters, being a close relative of the unknown “missing link” [Fe4(CO)12(μ4-O)] (2). In order to understand the stability of 1 relative to 2, we have carried out DFT calculations on [Fe4(CO)10L2(μ4-O)] (L = CO, PMe3, PPh3; L2 = dppn), which suggest that 1 is best considered as a combination of [Fe3(CO)9O]2− and [Fe(CO)(dppn)]2+ fragments." @default.
• W2003237289 created "2016-06-24" @default.
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• W2003237289 date "2009-11-30" @default.
• W2003237289 modified "2023-09-24" @default.
• W2003237289 title "Synthesis and Molecular Structure of [Fe₄(CO)₁₀(μ₄-O)(κ²-dppn)] (dppn = 1,8-bis(diphenylphosphino)naphthalene): A Missing Piece in the [M₄(CO)₁₂(μ₄-E)]^<i>n</i>− (M = Fe, Ru; E = C, N, O; <i>n</i> = 2, 1, 0) Puzzle" @default.
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• W2003237289 doi "https://doi.org/10.1021/om900855v" @default.
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