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- W2003239096 abstract "In this paper we present the results of an experimental study of the vacuum ultraviolet absorption spectra of Xe impurity in Ar (density range 0–1.4 g cmṫ) in Ne (density range 0.1–0.65 g cmṫ;) and in He (density range 0.04–0.1 g cmṫ;), spanning the energy region 8–11 eV. These experimental results provide new information regarding medium perturbations of the lowest extravalence impurity excitations and pertain to the observation of Wannier impurity states in a dense medium. We were able to identify low extravalence excitations of d symmetry which persist over the entire density range of the fluid. All the lowest extravalence excitations to states of s and d symmetry exhibit appreciable spectral blue-shifts at moderate and at high density of the fluid. New experimental evidence has been obtained for the identification of the n = 2 Wannier impurity state of Xe in liquid Ar, resulting in an estimate of the impurity ionization potential in the dense fluid. A qualitative relation has been established between the spectral shifts of the high Rydberg states in the atomic limit and the location of the n = 2 Wannier state as well as the impurity band gap in the liquid." @default.
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- W2003239096 date "1977-07-01" @default.
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- W2003239096 title "Experimental evidence for wannier impurity states in doped rare-gas fluids" @default.
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- W2003239096 doi "https://doi.org/10.1016/0301-0104(77)89040-x" @default.
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