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- W2003240060 abstract "The direct β-coupling of cyclic ketones with aryl ketones has been achieved via the synergistic combination of photoredox catalysis and organocatalysis. Diaryl oxymethyl or aryl–alkyl oxymethyl radicals, transiently generated via single-electron reduction of ketone precursors, readily merge with β-enaminyl radical species, generated by photon-induced enamine oxidation, to produce γ-hydroxyketone adducts. Experimental evidence indicates that two discrete reaction pathways can be operable in this process depending upon the nature of the ketyl radical precursor and the photocatalyst." @default.
- W2003240060 created "2016-06-24" @default.
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- W2003240060 date "2013-11-22" @default.
- W2003240060 modified "2023-10-13" @default.
- W2003240060 title "Direct β-Functionalization of Cyclic Ketones with Aryl Ketones via the Merger of Photoredox and Organocatalysis" @default.
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- W2003240060 doi "https://doi.org/10.1021/ja410478a" @default.
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