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- W2003240424 abstract "The reaction of [Cp* Ir(η5-C6H5O)][BF4] (1) with PPh3 in refluxing C2H4Cl2 afforded unexpectedly but reproducibly the known compound Cp* IrCl2PPh3 (2) which was identified by 1H-NMR spectroscopy and single crystal X-ray diffraction. This unexpected chemical transformation to give 2 involves ‘C-Cl’ abstraction from dichloroethane mediated by the ‘Cp* Ir’ fragment. A rationale for this surprising transformation is advanced." @default.
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- W2003240424 date "1997-12-01" @default.
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- W2003240424 title "Unexpected formation of Cp* IrCl2PPh3 from the reaction of [Cp* Ir(η5-C6H5O)][BF4] with PPh3 in dichloroethane involving C-Cl bond activation" @default.
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- W2003240424 doi "https://doi.org/10.1016/s0022-328x(97)00470-1" @default.
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