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• W2003249348 abstract "The diffusion of benzene in the high silica zeolite ZSM5 has been studied at various coverages by pulsed field gradient nuclear magnetic resonance (PFGNMR) and quasi-elastic neutron scattering (QUENS). The PFGNMR technique has probed inter- and intra-crystalline diffusion over the millisecond timescale giving intra coefficients of the order 10−10 m2 s−1 and inter coefficients in the range from 10−7 to 10−9 m2 s−1 with increasing coverage. This suggests a ‘viscous’ liquid-like environment inside the zeolite but rather faster diffusion between crystallites. QUENS has probed intra-crystalline diffusion on the nanosecond timescale giving results in the range 10−10 to 10−9 m2 s−1 at high coverages. A jump activation energy for this process of 5.0 ± 0.4 kJ mol−1 has been estimated over the temperature range of 213 to 343 K." @default.
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• W2003249348 date "1989-01-01" @default.
• W2003249348 modified "2023-09-27" @default.
• W2003249348 title "The diffusion of benzene in high silica zeolite ZSM5 studied by PFGNMR and QUENS" @default.
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• W2003249348 doi "https://doi.org/10.1016/0166-6622(89)80239-2" @default.
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