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• W2003257101 abstract "Reaction of ligand, L-CH2Ph with Pd(CH3CN)2Cl2 in acetonitrile in presence of PPh3 and subsequent addition of NaClO4 yielded Pd(II) complex, [Pd(L)(PPh3)](ClO4) 1 due to the SC (CH2Ph) bond cleavage during complexation. Complex 1 was characterized by spectral analysis and the structure was authenticated by single crystal X-ray diffraction. The diffraction analysis revealed that the monoanionic ligand binds with palladium (II) in (N, N, S) fashion in a distorted square planar geometry where the fourth position is occupied by one tri phenyl phosphine group. One ClO4− ion satisfies the charge of the former aggregate, [Pd(L)(PPh3)]+. The complex [Pd(L)(PPh3)](ClO4), 1 exhibits a very good catalytic activity towards CC bond formation." @default.
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• W2003257101 date "2015-03-01" @default.
• W2003257101 modified "2023-10-17" @default.
• W2003257101 title "Synthesis and characterization of palladium (II) complex of Schiff base ligand: CS bond cleavage and catalytic activity" @default.
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• W2003257101 doi "https://doi.org/10.1016/j.inoche.2015.01.018" @default.
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