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- W2003260025 abstract "A new one-dimensional phase, CsGaSe3 has been synthesized and characterized by single crystal X-ray diffraction, differential thermal analysis, and single crystal UV/Vis spectroscopy. The structure contains infinite chain anions, [GaSe(Se2)]— separated by Cs cations. The Ga3+ cation is in a distorted tetrahedral environment coordinated by each two Se2— and Se22— ions. The red crystals of CsGaSe3 absorb visible light at energies above 2.25 eV. Differential thermal analysis revealed that the compound does not melt below 1000 °C. Crystal data: CsGaSe3, monoclinic, space group P21/c (No 14), a=7.727(1), b=13.014(3), c=6.705(1), β=106.39(3)°, Z=4, R1=0.0469.Die eindimensionale Polyselenid-Verbindung CsGaSe3Eine neue eindimensionale Phase, CsGaSe3, wurde synthetisiert und durch Einkristall-Rontgenbeugung, Differentialthermoanalyse sowie durch Einkristall-UV/Vis-Spektroskopie charakterisiert. Die Struktur besteht aus unendlichen Anionen-Ketten, [GaSe(Se2)]—, die durch Cs-Kationen getrennt sind. Das Ga3+-Kation ist in verzerrt tetraedrischer Anordnung durch je zwei Se2—- und Se22—-Ionen koordiniert. Die roten Kristalle von CsGaSe3 absorbieren im sichtbaren Licht bei Energien uber 2, 225 eV. Die Differentialthermoanalyse zeigte, dass die Verbindung nicht unter 1000 °C schmilzt. Die Kristalldaten von CsGaSe3 sind: monoklin, Raumgruppe P21/c (No 14), a=7, 727(1), b=13, 014(3), c=6, 705(1)A, β=106, 39(3)°, Z=4, R1=0, 0469." @default.
- W2003260025 created "2016-06-24" @default.
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- W2003260025 date "2003-07-15" @default.
- W2003260025 modified "2023-09-27" @default.
- W2003260025 title "The One-Dimensional Polyselenide Compound CsGaSe3." @default.
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- W2003260025 doi "https://doi.org/10.1002/chin.200328006" @default.
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