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- W2003263224 abstract "It is shown that the effective breakdown constant k3,eff of the PS hydroperoxide (ROOH PS) measured from the ratio of the steady rate of oxidation to [ROOH]st and the kinetics of accumulation of ROOH rises with increase in the oxygen pressure. Breakdown of ROOH PS in vacuo takes place as a set of two monomolecular reactions with rate constants differing by a decimal order of magnitude. The fraction of the rapidly decaying hydroperoxide rises linearly with increase in the total concentration of ROOH. The authors postulate rapid breakdown of the polyfunctional polymer ROOHs, the rate of formation of which is proportional to [ROOH]. The kinetic scheme on the basis of this assumption quantitatively describes the experimental findings." @default.
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- W2003263224 date "1986-01-01" @default.
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- W2003263224 title "Kinetics and mechanism of the formation and breakdown of the hydroperoxide in the course of oxidation of polystyrene" @default.
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- W2003263224 doi "https://doi.org/10.1016/0032-3950(86)90398-9" @default.
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