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• W2003269938 abstract "β-Hydroxycarbonyls can be formed from the gas-phase reactions of alkenes with the OH radical, both in the presence and in the absence of NO. To date, because of analytical difficulties, few data have been reported for the formation of this class of compound from the reactions of the OH radical with alkenes. We have determined that β-hydroxyketones can be readily analyzed by gas chromatography, and in this work we have shown that in 1 atm of air the β-hydroxyalkoxy radicals formed in the reactions of the OH radical with trans-2-butene, trans-3-hexene, 1-butene, and α-pinene in the presence of NO primarily decompose rather than react with O2. Rate constant ratios kd/kO2 (or lower limits thereof), where kd and kO2 are respectively the rate constants for the decomposition and the reaction with O2 of the intermediate β-hydroxyalkoxy radicals, have been obtained for the reactions of the CH3CH(Ȯ)CH(OH)CH3, CH3CH2CH(Ȯ)CH2OH, and CH3CH2CH(Ȯ)CH(OH)CH2CH3 radicals at 296 ± 2 K and atmospheric pressure. Using the O3 reactions with the alkenes to generate OH radicals, the reactions of the OH radical with trans-2-butene, trans-3-hexene, and α-pinene in the absence of NO lead to the formation of the expected β-hydroxycarbonyls and (at least for trans-2-butene) the α,β-diol." @default.
• W2003269938 created "2016-06-24" @default.
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• W2003269938 date "2000-03-24" @default.
• W2003269938 modified "2023-10-18" @default.
• W2003269938 title "Formation of β-Hydroxycarbonyls from the OH Radical-Initiated Reactions of Selected Alkenes" @default.
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• W2003269938 doi "https://doi.org/10.1021/es991125a" @default.
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