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- W2003273324 abstract "Methane is activated at moderate temperature on polyoxometalates, leading to the evolution of hydrogen and the formation of a methoxy species which has been characterized by solid-state <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:mrow><mml:mtext>C</mml:mtext><mml:mrow><mml:mtext>13</mml:mtext></mml:mrow></mml:mrow></mml:math> CP-MAS NMR. In the case of a molybdic polyoxometalate, the methyl group is linked to an edge-shared oxygen atom of the polyoxometalate. Upon heating, it reacts with oxygens of the polyoxometalate resulting in the formation of formyl species and then carbon dioxide and a reduction of molybdenum. Upon treatment with water, only traces of methanol can be detected." @default.
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- W2003273324 date "2013-01-14" @default.
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- W2003273324 title "Methane Activation and Transformation on Polyoxometalates" @default.
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