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• W2003290334 endingPage "27" @default.
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• W2003290334 abstract "The reaction of dichlorido(cod)palladium(II) (cod = 1,5-cyclooctadiene) with 2-(benzylsulfanyl)aniline followed by heating in N , N -dimethylformamide (DMF) produces the linear trinuclear Pd 3 complex bis(μ 2 -1,3-benzothiazole-2-thiolato)bis[μ 2 -2-(benzylsulfanyl)anilinido]dichloridotripalladium(II) N , N -dimethylformamide disolvate, [Pd 3 (C 7 H 4 NS 2 ) 2 (C 13 H 12 NS) 2 Cl 2 ]·2C 3 H 7 NO. The molecule has overline{1} symmetry and a Pd...Pd separation of 3.2012 (4) Å. The outer Pd II atoms have a square-planar geometry formed by an N , S -chelating 2-(benzylsulfanyl)anilinide ligand, a chloride ligand and the thiolate S atom of a bridging 1,3-benzothiazole-2-thiolate ligand, while the central Pd II core shows an all N -coordinated square-planar geometry. The geometry is perfectly planar within the PdN 4 core and the N—Pd—N bond angles differ significantly [84.72 (15)° for the N atoms of ligands coordinated to the same outer Pd atom and 95.28 (15)° for the N atoms of ligands coordinated to different outer Pd atoms]. This trinuclear Pd 3 complex is the first example of one in which 1,3-benzothiazole-2-thiolate ligands are only N -coordinated to one Pd centre. The 1,3-benzothiazole-2-thiolate ligands were formed in situ from 2-(benzylsulfanyl)aniline." @default.
• W2003290334 created "2016-06-24" @default.
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• W2003290334 date "2013-12-14" @default.
• W2003290334 modified "2023-09-27" @default.
• W2003290334 title "A trinuclear palladium(II) complex containing<i>N</i>,<i>S</i>-coordinating 2-(benzylsulfanyl)anilinide and 1,3-benzothiazole-2-thiolate ligands with a central square-planar PdN₄motif" @default.
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• W2003290334 doi "https://doi.org/10.1107/s2053229613032828" @default.
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