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• W2003298081 abstract "Electrolytic water splitting has gained importance in recent years because of its promise of economic production without adversive environmental impact of hydrogen as a chemical, and particularly on a large scale, as an energy carrier for novel energy systems proposed for introduction in the near future. Reliable measurements of hydrogen and oxygen overvoltages are of key significance in the development of alkaline water electrolysis systems. In this paper, on the basis of the most recent values of the relevant thermodynamic parameters, precise equations were derived for measuring oxygen and hydrogen overvoltages by using the particularly suitable Hg/HgO/OH− as well as reversible hydrogen reference electrodes in the temperature range 20–200°C, overall pressure range 1–200 bar, and concentration range 0–18 m KOH or 0–25 m NaOH. Very good agreement was found between the theoretically computed and experimentally measured values of the equilibrium potential difference of the cell Hg/HgO/NaOH (or KOH) (m)/H2 for 1–17.6 m NaOH and 6–12 m KOH at 25 and 75°C and at atmospheric pressure. Equations were also derived for the equilibrium voltage of water electrolysis under standard and actual conditions in the temperature, pressure and alkali hydroxide concentration ranges mentioned above." @default.
• W2003298081 created "2016-06-24" @default.
• W2003298081 creator A5045525249 @default.
• W2003298081 date "1985-01-01" @default.
• W2003298081 modified "2023-10-02" @default.
• W2003298081 title "Determination of the oxygen and hydrogen overvoltage in concentrated alkali hydroxide solutions" @default.
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• W2003298081 doi "https://doi.org/10.1016/0360-3199(85)90062-x" @default.
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