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• W2003303539 abstract "The vibrational lifetimes of the O-H and O-D stretch modes in the perovskite oxide KTaO3 are measured by pump-probe infrared spectroscopy. Both stretch modes are exceptionally long lived and exhibit a large reverse isotope effect, due to a phonon-assisted proton-tunneling process, which involves the O-Ta-O bending motion. The excited-state tunneling rate is found to be 7 orders of magnitude larger than from the ground state in the proton conducting oxide, BaCeO3 [Phys. Rev. B 60, R3713 (1999)]." @default.
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• W2003303539 date "2009-02-20" @default.
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• W2003303539 title "Proton Tunneling: A Decay Channel of the O-H Stretch Mode in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mi>KTaO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math>" @default.
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• W2003303539 doi "https://doi.org/10.1103/physrevlett.102.075506" @default.
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