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• W2003303867 abstract "Resonance Raman spectroscopy has been applied to two distinct temporal species of indoleamine 2,3-dioxygenase during catalytic turnover. We have identified two oxygen-isotope-sensitive Raman modes at 569 and 798 cm−1 for the two respective species. The 16O18O analysis of the 798 cm−1 band indicates the existence of a ferryl-oxo heme, which is inconsistent with the previously proposed reaction mechanism. The present study thus provides a physical basis for the structures of the possible reaction intermediates." @default.
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• W2003303867 date "2010-01-05" @default.
• W2003303867 modified "2023-10-09" @default.
• W2003303867 title "Identification of the Fe–O₂and the Fe=O Heme Species for Indoleamine 2,3-Dioxygenase during Catalytic Turnover" @default.
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• W2003303867 doi "https://doi.org/10.1246/cl.2010.36" @default.
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