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- W2003304080 abstract "The hydroboration—oxidation of a variety of trimethylsilyl enol ethers has been investigated. The trimethylsiloxy group exerts a strong directive effect on the reaction to place the boron atom predominantly on the β carbon. The resulting β boryl intermediates undergo a facile elimination in the acyclic systems, but are much more stable in the cyclic systems. The reaction of the trimethylsilyl enol ethers of cyclic ketones gives either trans-1,2 diols or monosilylated trans-1,2 diols depending upon the work-up procedure." @default.
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- W2003304080 date "1974-08-01" @default.
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- W2003304080 title "The hydroboration of trimethylsilyl enol ethers" @default.
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- W2003304080 doi "https://doi.org/10.1016/s0022-328x(00)90309-7" @default.
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