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- W2003304854 abstract "Abstract Triphenylsilylsodium and methyldiphenylsilylsodium have been prepared in THF in 70–80% yields by reaction between the corresponding disilanes and sodium in the presence of small amounts of naphthalene or biphenyl, or between the corresponding disilanes or chlorosilanes and sodium in the presence of naphthalene. No silylsodium compounds were formed by the reaction of the chlorosilanes with sodium in the presence of biphenyl. Attempts to prepare dimethylphenylsilylsodium from 1,1,2,2-tetramethyl-1,2-diphenyldisilane and sodium in the presence of naphthalene or biphenyl failed. In these cases dimethylphenylsilyl-substituted derivatives of the hydrocarbons were isolated. Triphenylsilylsodium and methyldiphenylsilylsodium are approximately as stable as the established silyllithium compounds. In reactions with halogen-containing compounds the silylsodium compounds gave higher yields coupled products than the comparable silyllithium compounds." @default.
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- W2003304854 date "1967-09-01" @default.
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- W2003304854 title "The preparation and some reactions of triphenylsilylsodium and methyldiphenylsilylsodium" @default.
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- W2003304854 doi "https://doi.org/10.1016/s0022-328x(00)91011-8" @default.
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