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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003308501> ?p ?o ?g. }

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• W2003308501 abstract "β-Galf-(1→5)-β-Galf-(1→6)-α-Manp-(1→6)-α-Manp, the immunodominant epitope in the cell-wall galactomannan of Aspergillus fumigatus, was synthesized for the first time as its allyl glycoside. The key disaccharide glycosyl donor, 2,3,5,6-tetra-O-benzoyl-β-d-galactofuranosyl-(1→5)-2-O-acetyl-3,6-di-O-benzoyl-β-d-galactofuranosyl trichloroacetimidate (10), was constructed by 5-O-glycosylation of 1,2-O-isopropylidene-3,6-di-O-benzoyl-α-d-galactofuranose (4) with 2,3,5,6-tetra-O-benzoyl-β-d-galactofuranosyl trichloroacetimidate (5), followed by 1,2-O-deacetonation, acetylation, selective 1-O-deacetylation, and trichloroacetimidation. The target tetrasaccharide 16 was obtained by the condensation of allyl 2,3,4-tri-O-benzoyl-α-d-mannopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-mannopyranoside (14) as glycosyl acceptor with the disaccharide glycosyl donor 10, followed by deprotection." @default.
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• W2003308501 date "2005-01-01" @default.
• W2003308501 modified "2023-09-29" @default.
• W2003308501 title "First synthesis of the immunodominant β-galactofuranose-containing tetrasaccharide present in the cell wall of Aspergillus fumigatus" @default.
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• W2003308501 doi "https://doi.org/10.1016/j.carres.2004.10.019" @default.
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