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- W2003313288 abstract "The axiomatic theory of ideally glassy networks, which has proved effective in describing phase diagrams and properties of chalcogenide and oxide glasses and their foreign interfaces, is broadened here to include intermolecular interactions in hydrogen-bonded polyalcohols such as glycerol, monosaccharides (glucose), and the optimal bioprotective hydrogen-bonded disaccharide networks formed from trehalose. The methods of Lagrangian mechanics and Maxwellian scaffolds are useful at the molecular level when bonding hierarchies are characterized by constraint counting similar to the chemical methods used by Huckel and Pauling. Whereas Newtonian molecular dynamical methods are useful for simulating large-scale interactions for times of order $10phantom{rule{0.3em}{0ex}}mathrm{ps}$, constraint counting describes network properties on glassy (almost equilibrated) time scales which may be of cosmological order for oxide glasses or years for trehalose. The ideally glassy network of trehalose may consist of extensible tandem sandwich arrays." @default.
- W2003313288 created "2016-06-24" @default.
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- W2003313288 date "2006-01-30" @default.
- W2003313288 modified "2023-09-23" @default.
- W2003313288 title "Ideally glassy hydrogen-bonded networks" @default.
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- W2003313288 doi "https://doi.org/10.1103/physrevb.73.024210" @default.
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