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- W2003345929 abstract "The second-order rate constants for the nucleophilic replacement of fluorine by isopropoxide in 5,6,7,8-tetrafluoro- and 6,7,-difluoro-1,2,3,4-tetrahydro-9-alkenyl-1,4-methanonaphthalenes and related 9-alkyl systems have been measured. A factor of 6 - 7 separates the most reactive compounds [the 9- (4′-trifluoromethylbenzylidene) derivatives] from the least reactive compounds [the syn-9-isopropyl derivatives] in both the tetrafluoro- and difluoro-series. It is concluded for these small reactivity differences." @default.
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- W2003345929 date "1976-09-01" @default.
- W2003345929 modified "2023-10-14" @default.
- W2003345929 title "Nucleophilic substitution in 5,6,7,8-tetrafluoro- and 6,7-difluoro-1,2,3,4-tetrahydro-9-alkenyl-1,4-methanonaphthalenes and related compounds. A search for homoallylic conjugation" @default.
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- W2003345929 doi "https://doi.org/10.1016/s0022-1139(00)81647-4" @default.
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