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- W2003363640 abstract "Abstract The adsorption of CO on Ni(111) has been studied using infrared reflection-absorption spectroscopy combined with LEED, Auger electron spectroscopy, thermal desorption spectroscopy and work function measurements. At low CO coverage (θ = 0.05) CO adsorbs on threefold sites with a strecthing frequency given by ω CO = 1817 cm −1 . At θ = 0.30 all molecules have shifted to two-fold sites, and θ = 0.50, where a c(4 × 2) structure is observed, ω CO = 1910 cm −1 . At θ = 0.57, with a (√7/2) × √7/2)R19.1° structure, one quarter of the molecules are adsorbed on top of the nickel atoms with the others in two-fold sites. Molecules bonded on the top sites give rise to a band at 2045 cm −1 . The frequency shift due to dipole-dipole interactions is small compared with the shift resulting from bonding to different crystallographic sites." @default.
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- W2003363640 date "1979-04-01" @default.
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- W2003363640 title "The adsorption sites of CO on Ni(111) as determined by infrared reflection-absorption spectroscopy" @default.
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- W2003363640 doi "https://doi.org/10.1016/0039-6028(79)90495-3" @default.
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