Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003372293> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2003372293 endingPage "343" @default.
- W2003372293 startingPage "343" @default.
- W2003372293 abstract "Formation of the Pd(II)-induced thioether-derivatised subphthalocyanine Subpc(SR)66 (R = Et (ethyl) or Bz (benzyl)) aggregate at the toluene/glycerol interface was investigated by means of a new in situ spectrophotometric method using two-phase Couette flow (TPCF). The shear-forced orientation of the aggregate of Subpc(SR)66–Pd(II) complexes formed at the toluene/glycerol interface was studied by their linear dichroism (LD) spectra. The H-aggregate of the Subpc(SEt)66–Pd(II) complex gave no LD signal, but the J-aggregate of the Subpc(SBz)66–Pd(II) complex clearly afforded LD spectra at a wide range of rotation speeds, suggesting a longer J-aggregate structure in the Subpc(SBz)66–Pd(II) system. The relaxation kinetics of the shear-forced orientation of the Pd(II)–Subpc(SBz)66 aggregate were observed after stopping the rotation and analysing using a multi-exponential decay equation. By increasing the Subpc(SBz)66 concentration in toluene, the fast relaxation fraction of 6.6–7.5 seconds decreased and the slow relaxation fraction of 292–322 seconds increased. The results obtained in this study demonstrate that the TPCF method is useful for studying the size distribution of aggregates formed at liquid/liquid interfaces." @default.
- W2003372293 created "2016-06-24" @default.
- W2003372293 creator A5011873187 @default.
- W2003372293 creator A5089028173 @default.
- W2003372293 date "2006-01-01" @default.
- W2003372293 modified "2023-10-06" @default.
- W2003372293 title "Two-phase Couette flow linear dichroism measurement of the shear-forced orientation of a palladium(ii)-induced aggregate of thioether-derivatised subphthalocyanines at the toluene/glycerol interface" @default.
- W2003372293 cites W1984967704 @default.
- W2003372293 cites W1986801254 @default.
- W2003372293 cites W2011277385 @default.
- W2003372293 cites W2017509326 @default.
- W2003372293 cites W2017627877 @default.
- W2003372293 cites W2027537762 @default.
- W2003372293 cites W2029778318 @default.
- W2003372293 cites W2034078366 @default.
- W2003372293 cites W2050683008 @default.
- W2003372293 cites W2056437971 @default.
- W2003372293 cites W2057163860 @default.
- W2003372293 cites W2064210105 @default.
- W2003372293 cites W2065842944 @default.
- W2003372293 cites W2070364077 @default.
- W2003372293 cites W2074990819 @default.
- W2003372293 cites W2076635182 @default.
- W2003372293 cites W2081234221 @default.
- W2003372293 cites W2124091163 @default.
- W2003372293 cites W2142872302 @default.
- W2003372293 cites W2157890526 @default.
- W2003372293 cites W2395793949 @default.
- W2003372293 cites W2431248070 @default.
- W2003372293 cites W243175757 @default.
- W2003372293 doi "https://doi.org/10.1039/b517657c" @default.
- W2003372293 hasPublicationYear "2006" @default.
- W2003372293 type Work @default.
- W2003372293 sameAs 2003372293 @default.
- W2003372293 citedByCount "16" @default.
- W2003372293 countsByYear W20033722932012 @default.
- W2003372293 countsByYear W20033722932013 @default.
- W2003372293 countsByYear W20033722932014 @default.
- W2003372293 countsByYear W20033722932015 @default.
- W2003372293 countsByYear W20033722932017 @default.
- W2003372293 countsByYear W20033722932018 @default.
- W2003372293 countsByYear W20033722932021 @default.
- W2003372293 crossrefType "journal-article" @default.
- W2003372293 hasAuthorship W2003372293A5011873187 @default.
- W2003372293 hasAuthorship W2003372293A5089028173 @default.
- W2003372293 hasConcept C113196181 @default.
- W2003372293 hasConcept C178790620 @default.
- W2003372293 hasConcept C185592680 @default.
- W2003372293 hasConcept C2524010 @default.
- W2003372293 hasConcept C2778142098 @default.
- W2003372293 hasConcept C2779099160 @default.
- W2003372293 hasConcept C2779444094 @default.
- W2003372293 hasConcept C33923547 @default.
- W2003372293 hasConcept C38349280 @default.
- W2003372293 hasConcept C43617362 @default.
- W2003372293 hasConcept C44280652 @default.
- W2003372293 hasConcept C71240020 @default.
- W2003372293 hasConcept C8010536 @default.
- W2003372293 hasConceptScore W2003372293C113196181 @default.
- W2003372293 hasConceptScore W2003372293C178790620 @default.
- W2003372293 hasConceptScore W2003372293C185592680 @default.
- W2003372293 hasConceptScore W2003372293C2524010 @default.
- W2003372293 hasConceptScore W2003372293C2778142098 @default.
- W2003372293 hasConceptScore W2003372293C2779099160 @default.
- W2003372293 hasConceptScore W2003372293C2779444094 @default.
- W2003372293 hasConceptScore W2003372293C33923547 @default.
- W2003372293 hasConceptScore W2003372293C38349280 @default.
- W2003372293 hasConceptScore W2003372293C43617362 @default.
- W2003372293 hasConceptScore W2003372293C44280652 @default.
- W2003372293 hasConceptScore W2003372293C71240020 @default.
- W2003372293 hasConceptScore W2003372293C8010536 @default.
- W2003372293 hasIssue "3" @default.
- W2003372293 hasLocation W20033722931 @default.
- W2003372293 hasOpenAccess W2003372293 @default.
- W2003372293 hasPrimaryLocation W20033722931 @default.
- W2003372293 hasRelatedWork W2054051158 @default.
- W2003372293 hasRelatedWork W2068198467 @default.
- W2003372293 hasRelatedWork W2072594799 @default.
- W2003372293 hasRelatedWork W2120315652 @default.
- W2003372293 hasRelatedWork W2165896740 @default.
- W2003372293 hasRelatedWork W2626861271 @default.
- W2003372293 hasRelatedWork W2954419754 @default.
- W2003372293 hasRelatedWork W2964336173 @default.
- W2003372293 hasRelatedWork W4236579005 @default.
- W2003372293 hasRelatedWork W4294215054 @default.
- W2003372293 hasVolume "30" @default.
- W2003372293 isParatext "false" @default.
- W2003372293 isRetracted "false" @default.
- W2003372293 magId "2003372293" @default.
- W2003372293 workType "article" @default.