FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003375183> ?p ?o ?g. }

• W2003375183 endingPage "584" @default.
• W2003375183 startingPage "574" @default.
• W2003375183 abstract "Two new dithiolate copper(II) and nickel(II) complexes with the ligand tert-butyl N-(2-mercaptoethyl)-carbamate (Boc-SH) were prepared. Their structures were established to be [(Boc-S)2M], where M = Cu (1) and Ni (2) by using elemental analysis, thermal analysis, molar conductivity, FT-IR, Raman, UV/VIS, and ESR as well as EI-mass spectroscopic methods. The X-ray structure of the ligand Boc-SH was also determined. Spectral data showed that the carbamate ligand act as anioinic bidentate through one immine nitrogen and one thiolate sulfur donor atoms. The spectral techniques suggest that both complexes appear to have square planar geometries. The very low electrical conductance of the two complexes supports their neutral nature. The redox behaviors of the obtained complexes were also investigated by cyclic voltammetry. The monomeric nature of both complexes was assessed from their magnetic susceptibility values. The thermoanalytical data evidence that complex (2) is stable up to 165 °C and undergo complete decomposition, resulting in NiO as a residual product. The TEM image of the obtained oxide residue showed its nanosize cluster, suggesting that complex (2) may be used as a precursor for the formation of nanooxide. The methylation reactions of the two dithiolate complexes (1) and (2) with methyl iodide appear to occur intramolecularly at the metal(II)-bound dithiolates, forming the metal(II)-bound dithioether complexes [M(Boc-SCH3)2]I2 with clean second-order constants of 7.95 × 10−2 and 10.59 × 10−2 M−1 s−1, respectively." @default.
• W2003375183 created "2016-06-24" @default.
• W2003375183 creator A5019834958 @default.
• W2003375183 creator A5034053238 @default.
• W2003375183 creator A5050832855 @default.
• W2003375183 creator A5054908881 @default.
• W2003375183 creator A5061512771 @default.
• W2003375183 date "2014-02-01" @default.
• W2003375183 modified "2023-10-15" @default.
• W2003375183 title "Spectroscopic, electrochemical, and alkylation reactions: tert-Butyl N-(2-mercaptoethyl)carbamate copper(II) and nickel(II) complexes as structural mimics for the active site of thiolate-alkylating enzymes" @default.
• W2003375183 cites W1588853632 @default.
• W2003375183 cites W1605955229 @default.
• W2003375183 cites W1964430090 @default.
• W2003375183 cites W1964986962 @default.
• W2003375183 cites W1978450379 @default.
• W2003375183 cites W1984134606 @default.
• W2003375183 cites W1984733240 @default.
• W2003375183 cites W1985467496 @default.
• W2003375183 cites W1997350327 @default.
• W2003375183 cites W1998722626 @default.
• W2003375183 cites W2001845595 @default.
• W2003375183 cites W2002825885 @default.
• W2003375183 cites W2005559708 @default.
• W2003375183 cites W2005670638 @default.
• W2003375183 cites W2006948764 @default.
• W2003375183 cites W2007017020 @default.
• W2003375183 cites W2009347830 @default.
• W2003375183 cites W2011524623 @default.
• W2003375183 cites W2016672581 @default.
• W2003375183 cites W2018372330 @default.
• W2003375183 cites W2019503478 @default.
• W2003375183 cites W2024327355 @default.
• W2003375183 cites W2025811506 @default.
• W2003375183 cites W2028092801 @default.
• W2003375183 cites W2033889171 @default.
• W2003375183 cites W2037488072 @default.
• W2003375183 cites W2040138153 @default.
• W2003375183 cites W2040578086 @default.
• W2003375183 cites W2041114202 @default.
• W2003375183 cites W2043540854 @default.
• W2003375183 cites W2045467769 @default.
• W2003375183 cites W2048506235 @default.
• W2003375183 cites W2051567805 @default.
• W2003375183 cites W2053892020 @default.
• W2003375183 cites W2055292312 @default.
• W2003375183 cites W2055875059 @default.
• W2003375183 cites W2055978178 @default.
• W2003375183 cites W2058031499 @default.
• W2003375183 cites W2065782985 @default.
• W2003375183 cites W2069223499 @default.
• W2003375183 cites W2073124751 @default.
• W2003375183 cites W2078109068 @default.
• W2003375183 cites W2079662840 @default.
• W2003375183 cites W2084140210 @default.
• W2003375183 cites W2086270430 @default.
• W2003375183 cites W2115198671 @default.
• W2003375183 cites W2132500565 @default.
• W2003375183 cites W2153023761 @default.
• W2003375183 cites W2156067091 @default.
• W2003375183 cites W2160425259 @default.
• W2003375183 cites W2170481053 @default.
• W2003375183 cites W2786064907 @default.
• W2003375183 cites W4205907437 @default.
• W2003375183 doi "https://doi.org/10.1016/j.saa.2013.10.002" @default.
• W2003375183 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24290356" @default.
• W2003375183 hasPublicationYear "2014" @default.
• W2003375183 type Work @default.
• W2003375183 sameAs 2003375183 @default.
• W2003375183 citedByCount "4" @default.
• W2003375183 countsByYear W20033751832018 @default.
• W2003375183 countsByYear W20033751832020 @default.
• W2003375183 countsByYear W20033751832022 @default.
• W2003375183 crossrefType "journal-article" @default.
• W2003375183 hasAuthorship W2003375183A5019834958 @default.
• W2003375183 hasAuthorship W2003375183A5034053238 @default.
• W2003375183 hasAuthorship W2003375183A5050832855 @default.
• W2003375183 hasAuthorship W2003375183A5054908881 @default.
• W2003375183 hasAuthorship W2003375183A5061512771 @default.
• W2003375183 hasConcept C116569031 @default.
• W2003375183 hasConcept C136957603 @default.
• W2003375183 hasConcept C147789679 @default.
• W2003375183 hasConcept C155647269 @default.
• W2003375183 hasConcept C160434732 @default.
• W2003375183 hasConcept C170493617 @default.
• W2003375183 hasConcept C17525397 @default.
• W2003375183 hasConcept C178516000 @default.
• W2003375183 hasConcept C178790620 @default.
• W2003375183 hasConcept C179104552 @default.
• W2003375183 hasConcept C185592680 @default.
• W2003375183 hasConcept C2777545050 @default.
• W2003375183 hasConcept C2777869211 @default.
• W2003375183 hasConcept C2780073701 @default.
• W2003375183 hasConcept C504270822 @default.
• W2003375183 hasConcept C52859227 @default.
• W2003375183 hasConcept C544153396 @default.
• W2003375183 hasConcept C544778455 @default.
• W2003375183 hasConcept C55493867 @default.
• W2003375183 hasConcept C8010536 @default.

• next