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- W2003404062 abstract "Among the three types of reagents from PhMgX (X=Br, Cl) and CuCN for phenylation of 4-cyclopentene-1,3-diol monoacetate, PhMgCl/CuCN (cat.) and Ph2Cu(CN)(MgCl)2 in THF afforded the trans-1,4-isomer efficiently (82–87% yields, 91–93% regioselectivity). Similarly, o- and p-RC6H4MgCl (R=Me, OMe, CH2CH) in combination with CuCN furnished good to excellent reactivity and regioselectivity. As an application, a three-step synthesis of dihydromultifidene was accomplished successfully." @default.
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- W2003404062 date "2003-05-01" @default.
- W2003404062 modified "2023-10-12" @default.
- W2003404062 title "A new reagent system for installation of an aryl group onto the monoacetate of 4-cyclopentene-1,3-diol" @default.
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- W2003404062 doi "https://doi.org/10.1016/s0040-4039(03)00777-9" @default.
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