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- W2003443459 abstract "The catalytic use of highly efficient poly(N-vinyl-2-pyrrolidone)-stabilized palladium–platinum nanoparticles (4.2 ± 1.9 nm) in the hydrolysis of ammonia-borane is reported. The catalyst is prepared by co-reduction of two metal ions in ethanol/water mixture by an alcohol reduction method and characterized by transmission electron microscopy, X-ray photoelectron spectroscopy and UV–Vis spectroscopy. They are recyclable and highly active for hydrogen generation from the hydrolysis of ammonia-borane even at very low concentrations and temperature, providing a record numbers of average turnover frequency value (125 mol H2/mol cat.min−1) and maximum hydrogen generation rate (3468 L H2 min−1 (mol cat)−1). They also provide activation energy of 51.7 ± 2 kJ/mol for the hydrolysis of ammonia borane." @default.
- W2003443459 created "2016-06-24" @default.
- W2003443459 creator A5037571474 @default.
- W2003443459 date "2015-02-01" @default.
- W2003443459 modified "2023-10-18" @default.
- W2003443459 title "Poly(N-vinyl-2-pyrrolidone)-stabilized palladium–platinum nanoparticles-catalyzed hydrolysis of ammonia borane for hydrogen generation" @default.
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- W2003443459 doi "https://doi.org/10.1016/j.jpowsour.2014.11.146" @default.
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