FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003443678> ?p ?o ?g. }

• W2003443678 endingPage "7085" @default.
• W2003443678 startingPage "7075" @default.
• W2003443678 abstract "The reversible kinetics of l-lactide bulk polymerization with tin(II) ethylhexanoate was determined over a wide range of temperatures, 130−220 °C, and monomer to initiator molar ratios, 1000−80 000. Both polymerization and depolymerization are accurately described by a reversible model with a propagation term that is first order in monomer and catalyst. The activation energy of propagation is 70.9 ± 1.5 kJ mol-1. The enthalpy, entropy, and ceiling temperature of polymerization are −23.3 ± 1.5 kJ mol-1, −22.0 ± 3.2 J mol-1 K-1, and 786 ± 87 °C, respectively. Crystallization increases the propagation rate and decreases the apparent monomer equilibrium in proportion to the degree of crystallinity. Natural hydroxyl impurities stoichiometrically control the polymer molecular weight but do not significantly affect the propagation rate." @default.
• W2003443678 created "2016-06-24" @default.
• W2003443678 creator A5013062068 @default.
• W2003443678 creator A5026124384 @default.
• W2003443678 creator A5087903826 @default.
• W2003443678 date "1997-11-01" @default.
• W2003443678 modified "2023-10-16" @default.
• W2003443678 title "Reversible Kinetics and Thermodynamics of the Homopolymerization of <scp>l</scp>-Lactide with 2-Ethylhexanoic Acid Tin(II) Salt" @default.
• W2003443678 cites W1523485552 @default.
• W2003443678 cites W1584381260 @default.
• W2003443678 cites W1588514918 @default.
• W2003443678 cites W1605684568 @default.
• W2003443678 cites W1883816835 @default.
• W2003443678 cites W1885597897 @default.
• W2003443678 cites W1972437965 @default.
• W2003443678 cites W1986770324 @default.
• W2003443678 cites W1994095222 @default.
• W2003443678 cites W2016077890 @default.
• W2003443678 cites W2020221643 @default.
• W2003443678 cites W2025592026 @default.
• W2003443678 cites W2027210775 @default.
• W2003443678 cites W2057069446 @default.
• W2003443678 cites W2057866636 @default.
• W2003443678 cites W2058365000 @default.
• W2003443678 cites W2059022198 @default.
• W2003443678 cites W2066468072 @default.
• W2003443678 cites W2068442209 @default.
• W2003443678 cites W2073589537 @default.
• W2003443678 cites W2084768877 @default.
• W2003443678 cites W2088734849 @default.
• W2003443678 cites W2090994478 @default.
• W2003443678 cites W2095405145 @default.
• W2003443678 cites W2139574761 @default.
• W2003443678 cites W2325464466 @default.
• W2003443678 cites W2325667068 @default.
• W2003443678 cites W2333152595 @default.
• W2003443678 cites W4251032101 @default.
• W2003443678 doi "https://doi.org/10.1021/ma970631m" @default.
• W2003443678 hasPublicationYear "1997" @default.
• W2003443678 type Work @default.
• W2003443678 sameAs 2003443678 @default.
• W2003443678 citedByCount "231" @default.
• W2003443678 countsByYear W20034436782012 @default.
• W2003443678 countsByYear W20034436782013 @default.
• W2003443678 countsByYear W20034436782014 @default.
• W2003443678 countsByYear W20034436782015 @default.
• W2003443678 countsByYear W20034436782016 @default.
• W2003443678 countsByYear W20034436782017 @default.
• W2003443678 countsByYear W20034436782018 @default.
• W2003443678 countsByYear W20034436782019 @default.
• W2003443678 countsByYear W20034436782020 @default.
• W2003443678 countsByYear W20034436782021 @default.
• W2003443678 countsByYear W20034436782022 @default.
• W2003443678 countsByYear W20034436782023 @default.
• W2003443678 crossrefType "journal-article" @default.
• W2003443678 hasAuthorship W2003443678A5013062068 @default.
• W2003443678 hasAuthorship W2003443678A5026124384 @default.
• W2003443678 hasAuthorship W2003443678A5087903826 @default.
• W2003443678 hasConcept C121332964 @default.
• W2003443678 hasConcept C147789679 @default.
• W2003443678 hasConcept C148898269 @default.
• W2003443678 hasConcept C166940927 @default.
• W2003443678 hasConcept C178790620 @default.
• W2003443678 hasConcept C185592680 @default.
• W2003443678 hasConcept C188027245 @default.
• W2003443678 hasConcept C203897987 @default.
• W2003443678 hasConcept C3288061 @default.
• W2003443678 hasConcept C38087914 @default.
• W2003443678 hasConcept C44228677 @default.
• W2003443678 hasConcept C46275449 @default.
• W2003443678 hasConcept C49852136 @default.
• W2003443678 hasConcept C521977710 @default.
• W2003443678 hasConcept C62520636 @default.
• W2003443678 hasConcept C8010536 @default.
• W2003443678 hasConcept C95121573 @default.
• W2003443678 hasConcept C97355855 @default.
• W2003443678 hasConceptScore W2003443678C121332964 @default.
• W2003443678 hasConceptScore W2003443678C147789679 @default.
• W2003443678 hasConceptScore W2003443678C148898269 @default.
• W2003443678 hasConceptScore W2003443678C166940927 @default.
• W2003443678 hasConceptScore W2003443678C178790620 @default.
• W2003443678 hasConceptScore W2003443678C185592680 @default.
• W2003443678 hasConceptScore W2003443678C188027245 @default.
• W2003443678 hasConceptScore W2003443678C203897987 @default.
• W2003443678 hasConceptScore W2003443678C3288061 @default.
• W2003443678 hasConceptScore W2003443678C38087914 @default.
• W2003443678 hasConceptScore W2003443678C44228677 @default.
• W2003443678 hasConceptScore W2003443678C46275449 @default.
• W2003443678 hasConceptScore W2003443678C49852136 @default.
• W2003443678 hasConceptScore W2003443678C521977710 @default.
• W2003443678 hasConceptScore W2003443678C62520636 @default.
• W2003443678 hasConceptScore W2003443678C8010536 @default.
• W2003443678 hasConceptScore W2003443678C95121573 @default.
• W2003443678 hasConceptScore W2003443678C97355855 @default.
• W2003443678 hasIssue "23" @default.
• W2003443678 hasLocation W20034436781 @default.
• W2003443678 hasOpenAccess W2003443678 @default.
• W2003443678 hasPrimaryLocation W20034436781 @default.

• next