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- W2003448538 abstract "Abstract D.C. susceptibility and zero field Mossbauer spectroscopy measurements are used to characterize the low-temperature magnetism of α-Rb2FeF5 · H2O and α-Cs2FeF5 · H2O. The compounds are rigorously isotypic quasi-1D Heisenberg magnets based on hydrogen bonded chains of-{FeF5H2O}2- - pseudo-octahedra with intervening Rb+ and Cs+ cations that enhance the low dimensionality. The 1D antiferromagnetic effects appear comparable, Txmax(1D) ∼5 K, while their 3D ordering temperatures are quite different, TN(Rb+) = 4.0 K, TN (Cs+) = 2.7 K. The internal hyperfine fields extrapolated to T = 0 K are ∼ 51 T suggesting zero point spin reduction (∼15%) consistent with 1D behavior. High field d.c. susceptibility measurements for polycrystalline Cs2FeF5 · H2O suggest spin-flop behavior with HSF" @default.
- W2003448538 created "2016-06-24" @default.
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- W2003448538 date "1994-08-01" @default.
- W2003448538 modified "2023-10-01" @default.
- W2003448538 title "Low-Temperature Antiferromagnetic Behavior of α-Rb2FeF5 · H2O and α-Cs2FeF5 · H2O" @default.
- W2003448538 doi "https://doi.org/10.1006/jssc.1994.1230" @default.
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