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- W2003451873 abstract "Stereoisomerization of 2-butenes and cross-metathesis of 2-butenes with 1-butene have been studied over MoO3/Al2O3 AND Re2O7/Al2O3 catalysts. Stereoisomerization over MoO3/A2O3 was found to proceed via both meta-thesis and in a non-metathetic way. Over Re2O7/Al2O3, where non-metathetic isomerization can be excluded, the rate of Stereoisomerization was higher for trans- than for cis-2-butene. The characteristics for cross-metathesis were as follows: selective formation of trans-2-pentene in trans-2-butene + 1-butene mixtures; formation of more propene than pentenes, especially in mixtures containing more 1-butene than 2-butene; lower rate of cross-meta-thesis in mixtures containing cis-2-butene than that in mixtures containing trans-2-butene." @default.
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- W2003451873 title "Stereochemistry in cross-metathesis of 1-butene with CIS- and TRANS-2-butene over MoO3/Al2O3 AND Re2O7/Al2O3 catalysts" @default.
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- W2003451873 doi "https://doi.org/10.1016/0304-5102(85)87026-7" @default.
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