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• W2003456187 abstract "A new tetranuclear complex [Fe4L2(μ-O)2(μ->OH)2](ClO4)4·H2O (1), (HL = N,N,N′,N′-tetrakis-[(2-pyridyl)methyl]-2-hydroxypropane-1,3-diamine) has been synthesized and its crystal structure and magnetic properties are shown. X-ray crystallography reveals that complex 1 contains a quadruply-charged, tetranuclear iron(III) cation and four perchlorate anions. In 1, the Fe4O6 core is composed of a tetrahedron of iron atoms bridged by six oxygen atoms (two oxo, two hydroxo, and two alkoxo groups from L). This results in an adamantane-type geometry with the iron atoms occupying the bridgehead positions. Susceptibility data of 1 indicate strong intramolecular antiferromagnetic coupling of high-spin FeIII atoms." @default.
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• W2003456187 date "2007-03-01" @default.
• W2003456187 modified "2023-10-14" @default.
• W2003456187 title "Synthesis, Structure and Magnetic Property of an “Adamantane” Type Tetranuclear Iron(III) Complex" @default.
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• W2003456187 doi "https://doi.org/10.1002/zaac.200600301" @default.
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