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- W2003456441 abstract "The rotational structure in the lowest Rydberg complex of hydrogen chloride, [X2Π]4sσ, was reinvestigated. The study is limited to the spectrum of D35Cl, the HCl bands being too diffuse for a detailed analysis of second-order effects. The Λ-type doubling in both component states, b3Πi and C1Π, is small since it arises from the uncoupling of the core rather than Rydberg orbital angular momentum. It can be interpreted in terms of pure precession relations that are known to exist between the ground and first excited states of DCl+. By contrast, the spin-orbit interactions, also originating in the core, are strong. In addition to distorting the triplet splitting in b3Π, they lead to an avoided crossing between the nearly coinciding levels b3Π0 (v = 1) and C1Π1 (v = 0). They are also responsible for anomalies in the b3Π0 ← X1Σ+ R-branch intensities of DCl as well as of HBr, DBr, and HI. From the J values at the observed R-branch minima we have estimated the ratio μ∥μ⊥ of the transition moments associated with the excitation of a 3pσ or 3pπ core electron to the 4sσ Rydberg orbital of DCl and, correspondingly, of the other hydrogen halides." @default.
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- W2003456441 date "1983-02-01" @default.
- W2003456441 modified "2023-09-23" @default.
- W2003456441 title "Rydberg states with a 2Π core: The b3Πi and C1Π states of DCl" @default.
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- W2003456441 doi "https://doi.org/10.1016/0022-2852(83)90276-x" @default.
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