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• W2003456786 abstract "We demonstrate markedly enhanced adhesion between oxide ceramics and conducting metals via promoting open-shell electronic structure at the interface, by using a more covalent oxide or doping with early transition metals. Open-shell character suppresses closed-shell repulsions and permits local covalent and/or donor-acceptor bonding, even in the absence of a conventional reaction layer. The dramatic impact of such local bonding attractions, predicted from density-functional calculations, contradicts the idea of classical electrostatic forces dominating metal-oxide adhesion." @default.
• W2003456786 created "2016-06-24" @default.
• W2003456786 creator A5004810716 @default.
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• W2003456786 date "2002-09-25" @default.
• W2003456786 modified "2023-10-02" @default.
• W2003456786 title "Importance of open-shell effects in adhesion at metal-ceramic interfaces" @default.
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• W2003456786 doi "https://doi.org/10.1103/physrevb.66.100103" @default.
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