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- W2003459654 abstract "Effects of interatomic separation on superexchange interactions and interatomic binding in Cu0.5Fe0.5Rh2SexS4 − x (0 ⩽x ⩽2) have been studied by Mössbauer, X-ray and magnetic-susceptibility techniques. The crystal structure is found to be a cubic spinel, and lattice constant a0 increases linearly with increasing selenium concentration. Temperature dependence of the magnetic hyperfine field at each site follows the Brillouin function for S = 52. The longer-range superexchange interaction between second-nearest Fe neighbors is weakened much more rapidly by increase of interatomic separation than that between first-nearest Fe neighbors. As interatomic distance increases, both Néel and Debye temperatures decrease exponentially while magnetic hyperfine field decreases linearly." @default.
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- W2003459654 date "1997-05-01" @default.
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- W2003459654 title "Mössbauer study of Cu0.5Fe0.5Rh2SexS4 −x" @default.
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- W2003459654 doi "https://doi.org/10.1016/s0022-3697(96)00181-3" @default.
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