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• W2003463267 abstract "Kinetic data obtained from a number of different investigators on the reaction of S(IV) with ozone in aqueous solution have been analyzed in terms of a single self-consistent rate expression. The rate expression that most appropriately fits all kinetic observations treated in this study is: −d[S(IV)]/dt = (k0α0 + k1α1 + k2α2)[S(IV)][O3] where α0, α1, and α2 denote the fraction of S(IV) in the form of SO2·H2O, HSO−3 and SO2−3, respectively. This kinetic expression is similar in form to the empirical rate laws reported by Erickson et al. (1977, Atmospheric Environment11, 813–817) and Hoigne et al. (1985, Water Res. 19, 993–1004). The recommended values for k0, k1 and k2 are (2.4 ± 1.1) × 104 M−1 s−1, (3.7 ± 0.7) × 105 M−1 s−1, and (1.5 ± 0.6) × 109 M−1 s−1, respectively. The activation energies that are recommended for k1 and k2 are taken from Erickson et al. (1977) as 46.0 kJ mol−1 and 43.9 kJ mol−1, respectively. The reaction proceeds via three independent pathways that involve a nucleophilic attack on ozone by SO2−3, HO-SO−2, and SO2·H2O. Rate laws and kinetic data of five investigators are compared for an open cloud water system with a liquid water content of 0.2 g m−3." @default.
• W2003463267 created "2016-06-24" @default.
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• W2003463267 date "1986-01-01" @default.
• W2003463267 modified "2023-09-26" @default.
• W2003463267 title "On the kinetics and mechanism of oxidation of aquated sulfur dioxide by ozone" @default.
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• W2003463267 doi "https://doi.org/10.1016/0004-6981(86)90147-2" @default.
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