Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003519862> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2003519862 endingPage "2778" @default.
- W2003519862 startingPage "2772" @default.
- W2003519862 abstract "The effect of the addition of 0−70% (v/v) acetonitrile (AcCN) as organic modifier, into a buffer solution containing 0−60 mmol L-1 sodium dodecyl sulfate (SDS), on the electrokinetic behavior of neutral hydrophobic compounds has been studied experimentally. The effective mobilities of the hydrophobic compounds sharply decreased above a certain AcCN concentration, depending to some extent on the SDS concentration. In solutions with up to 40% AcCN, with SDS concentrations below the literature values of the critical micelle concentration, neutral hydrophobic analytes still showed a considerable electrophoretic mobility. The observed mobilities were too high to be attributed to solvophobic interaction of the analytes with single SDS ions. From conductivity measurements, a strong indication was found that increasing the fraction of AcCN in the SDS solution does not lead to a complete disintegration of the micelles. Even with high AcCN concentrations, the mechanism of the separation was found to be a distribution between the aqueous phase and micelle-like SDS aggregates. The influence of the addition of AcCN on the mobilities could be explained as the combined effect of a decrease of the micellar volume fraction, a change of the micellar properties, and a decrease of the distribution constants of the analytes." @default.
- W2003519862 created "2016-06-24" @default.
- W2003519862 creator A5005318241 @default.
- W2003519862 creator A5035527719 @default.
- W2003519862 creator A5048449675 @default.
- W2003519862 date "1997-07-01" @default.
- W2003519862 modified "2023-10-14" @default.
- W2003519862 title "Mechanism of Electrokinetic Separations of Hydrophobic Compounds with Sodium Dodecyl Sulfate in Acetonitrile−Water Mixtures" @default.
- W2003519862 cites W1964049605 @default.
- W2003519862 cites W1964781186 @default.
- W2003519862 cites W1967441316 @default.
- W2003519862 cites W1969494392 @default.
- W2003519862 cites W1981874024 @default.
- W2003519862 cites W1983971169 @default.
- W2003519862 cites W1986996617 @default.
- W2003519862 cites W2000820857 @default.
- W2003519862 cites W2004847550 @default.
- W2003519862 cites W2008511442 @default.
- W2003519862 cites W2025587532 @default.
- W2003519862 cites W2025681873 @default.
- W2003519862 cites W2030782061 @default.
- W2003519862 cites W2035637823 @default.
- W2003519862 cites W2052273644 @default.
- W2003519862 cites W2063139866 @default.
- W2003519862 cites W2076499156 @default.
- W2003519862 cites W2076848547 @default.
- W2003519862 cites W2143303707 @default.
- W2003519862 doi "https://doi.org/10.1021/ac961257b" @default.
- W2003519862 hasPublicationYear "1997" @default.
- W2003519862 type Work @default.
- W2003519862 sameAs 2003519862 @default.
- W2003519862 citedByCount "54" @default.
- W2003519862 countsByYear W20035198622012 @default.
- W2003519862 countsByYear W20035198622013 @default.
- W2003519862 countsByYear W20035198622014 @default.
- W2003519862 countsByYear W20035198622016 @default.
- W2003519862 countsByYear W20035198622017 @default.
- W2003519862 countsByYear W20035198622018 @default.
- W2003519862 countsByYear W20035198622020 @default.
- W2003519862 countsByYear W20035198622022 @default.
- W2003519862 crossrefType "journal-article" @default.
- W2003519862 hasAuthorship W2003519862A5005318241 @default.
- W2003519862 hasAuthorship W2003519862A5035527719 @default.
- W2003519862 hasAuthorship W2003519862A5048449675 @default.
- W2003519862 hasBestOaLocation W20035198622 @default.
- W2003519862 hasConcept C11268172 @default.
- W2003519862 hasConcept C147789679 @default.
- W2003519862 hasConcept C166361863 @default.
- W2003519862 hasConcept C178790620 @default.
- W2003519862 hasConcept C179104552 @default.
- W2003519862 hasConcept C184651966 @default.
- W2003519862 hasConcept C185592680 @default.
- W2003519862 hasConcept C27703432 @default.
- W2003519862 hasConcept C2777463227 @default.
- W2003519862 hasConcept C2778913249 @default.
- W2003519862 hasConcept C32909587 @default.
- W2003519862 hasConcept C40250595 @default.
- W2003519862 hasConcept C43617362 @default.
- W2003519862 hasConcept C49511088 @default.
- W2003519862 hasConcept C64237528 @default.
- W2003519862 hasConcept C90260826 @default.
- W2003519862 hasConceptScore W2003519862C11268172 @default.
- W2003519862 hasConceptScore W2003519862C147789679 @default.
- W2003519862 hasConceptScore W2003519862C166361863 @default.
- W2003519862 hasConceptScore W2003519862C178790620 @default.
- W2003519862 hasConceptScore W2003519862C179104552 @default.
- W2003519862 hasConceptScore W2003519862C184651966 @default.
- W2003519862 hasConceptScore W2003519862C185592680 @default.
- W2003519862 hasConceptScore W2003519862C27703432 @default.
- W2003519862 hasConceptScore W2003519862C2777463227 @default.
- W2003519862 hasConceptScore W2003519862C2778913249 @default.
- W2003519862 hasConceptScore W2003519862C32909587 @default.
- W2003519862 hasConceptScore W2003519862C40250595 @default.
- W2003519862 hasConceptScore W2003519862C43617362 @default.
- W2003519862 hasConceptScore W2003519862C49511088 @default.
- W2003519862 hasConceptScore W2003519862C64237528 @default.
- W2003519862 hasConceptScore W2003519862C90260826 @default.
- W2003519862 hasIssue "14" @default.
- W2003519862 hasLocation W20035198621 @default.
- W2003519862 hasLocation W20035198622 @default.
- W2003519862 hasOpenAccess W2003519862 @default.
- W2003519862 hasPrimaryLocation W20035198621 @default.
- W2003519862 hasRelatedWork W18163392 @default.
- W2003519862 hasRelatedWork W1970108421 @default.
- W2003519862 hasRelatedWork W1976452829 @default.
- W2003519862 hasRelatedWork W1982828281 @default.
- W2003519862 hasRelatedWork W1999497496 @default.
- W2003519862 hasRelatedWork W2005129447 @default.
- W2003519862 hasRelatedWork W2037977809 @default.
- W2003519862 hasRelatedWork W2095985475 @default.
- W2003519862 hasRelatedWork W2355915299 @default.
- W2003519862 hasRelatedWork W2802882301 @default.
- W2003519862 hasVolume "69" @default.
- W2003519862 isParatext "false" @default.
- W2003519862 isRetracted "false" @default.
- W2003519862 magId "2003519862" @default.
- W2003519862 workType "article" @default.