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• W2003541754 startingPage "245101" @default.
• W2003541754 abstract "Long-term physical ageing of chalcogenide glasses, which occurs over tens of years, is much less understood than the short-term ageing. With Se-rich underconstrained As30Se70 glass as a model composition (consisting of Sen chains with n≤3 on average), a microscopic model is developed for this phenomenon by combining information from differential scanning calorimetry, extended x-ray absorption fine structure, Raman, and 77Se solid state nuclear magnetic resonance spectroscopies. The accompanying changes in the electronic structure of these glasses are investigated by x-ray photoelectron spectroscopy. The data suggest ageing from cooperative relaxation, presumably involving bond switching or reconfiguration of As–Se–Se–As fragments." @default.
• W2003541754 created "2016-06-24" @default.
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• W2003541754 date "2008-05-22" @default.
• W2003541754 modified "2023-10-16" @default.
• W2003541754 title "Long-term physical ageing in As–Se glasses with short chalcogen chains" @default.
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• W2003541754 doi "https://doi.org/10.1088/0953-8984/20/24/245101" @default.
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