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- W2003602016 abstract "The electron transmission spectra of selenophene and tellurophene were recorded in the 0–6 eV energy range. Two resonances associated with the addition of electrons to the 3b1 and 2a2 (π*) MOs were identified. An additional resonance, which is not present in the spectra of furan and thiophene, was observed in selenophene and tellurophene. Xα calculations indicate that this additional resonance is caused by electron capture into a σ* MO with strong heteroatom “d” character. The energy trends of the anion states in the series of chalcophenes, C4H4X (X = O, S, Se, Te), are discussed in terms of d/π* mixing and of geometrical variations." @default.
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- W2003602016 date "1984-08-01" @default.
- W2003602016 modified "2023-09-23" @default.
- W2003602016 title "Electron transmission spectra of selenophene and tellurophene and Xα computations of electron affinities for chalcophenes" @default.
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- W2003602016 doi "https://doi.org/10.1016/0301-0104(84)87011-1" @default.
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