FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003620147> ?p ?o ?g. }

• W2003620147 endingPage "123" @default.
• W2003620147 startingPage "111" @default.
• W2003620147 abstract "The reaction of a new iridium reagent [Ir(η4-1,5-Me2COD)Cl]2 (1) with [nido-7,8-μ-(1′,2′-CH2C6H4CH2)-7,8-C2B9H10]−K+ (2) in solution of C6H6–MeOH mixture or in C6H6 afforded either an agostic (CH⋯Ir) closo-3-[η3-(endo-1,5-Me2COD)]-1,2-μ-(1′,2′-CH2C6H4CH2)-3,1,2-IrC2B9H9 (3) along with closo-3-[η3-(endo-1,5-Me2COD)]-1,2-μ-(1′,2′-CH2C6H4CH2)-8-(EtO)-3,1,2-IrC2B9H8 (4) or the only complex 3 in high yield. Complex 3 in dichloromethane solution is quantitatively converted to isomeric η3-exo-allylic complex closo-3-[η3-(1-exo-CH2-5-MeC8H12)]-1,2-μ-[η2-(1′,2′-CH2C6H4CH2)]-3,1,2-IrC2B9H9 (5) for a few days. All new complexes 3, 4 and 5 were characterized by single-crystal X-ray diffraction studies, which confirmed the existence of an agostic CH⋯Ir interaction in 3 and revealed a weak η2-coordination of the metal atom with one of the aromatic bonds of ortho-xylylene cage substituent in 5. The normal and low-temperature 1H- and 13C/13C{1H}-NMR spectra as well as 2D COSY/HETCOR NMR data obtained for the studied complexes are discussed in details." @default.
• W2003620147 created "2016-06-24" @default.
• W2003620147 creator A5019355825 @default.
• W2003620147 creator A5041745355 @default.
• W2003620147 creator A5075891808 @default.
• W2003620147 creator A5081870737 @default.
• W2003620147 creator A5082532445 @default.
• W2003620147 creator A5091875084 @default.
• W2003620147 date "2003-08-01" @default.
• W2003620147 modified "2023-09-26" @default.
• W2003620147 title "First agostic closo-metallacarboranes with η3-cyclooctenyl type ligand: synthesis and structural characterization of closo-3-[η3-(endo-1,5-dimethylcycloocten-1-yl)]-1,2-μ-(1′,2′-xylylene)-3,1,2-IrC2B9H9 and its isomerization to closo-3-[η3-(exo-1-methylene-5-methylcyclooctene-1-yl)]-1,2-μ-[η2-(1′,2′-xylylene)]-3,1,2-IrC2B9H9" @default.
• W2003620147 cites W1516794507 @default.
• W2003620147 cites W1544966137 @default.
• W2003620147 cites W1972714347 @default.
• W2003620147 cites W1975500584 @default.
• W2003620147 cites W1979580053 @default.
• W2003620147 cites W1979669988 @default.
• W2003620147 cites W1979925983 @default.
• W2003620147 cites W1984461482 @default.
• W2003620147 cites W1987541414 @default.
• W2003620147 cites W1994282234 @default.
• W2003620147 cites W1999980397 @default.
• W2003620147 cites W2001825533 @default.
• W2003620147 cites W2007660039 @default.
• W2003620147 cites W2008459639 @default.
• W2003620147 cites W2010726020 @default.
• W2003620147 cites W2011233508 @default.
• W2003620147 cites W2011610935 @default.
• W2003620147 cites W2015405793 @default.
• W2003620147 cites W2019291112 @default.
• W2003620147 cites W2019731705 @default.
• W2003620147 cites W2023064793 @default.
• W2003620147 cites W2026754812 @default.
• W2003620147 cites W2029579258 @default.
• W2003620147 cites W2033015253 @default.
• W2003620147 cites W2046974590 @default.
• W2003620147 cites W2049989483 @default.
• W2003620147 cites W2056519048 @default.
• W2003620147 cites W2058559161 @default.
• W2003620147 cites W2059376925 @default.
• W2003620147 cites W2059580933 @default.
• W2003620147 cites W2067673300 @default.
• W2003620147 cites W2068560713 @default.
• W2003620147 cites W2087258277 @default.
• W2003620147 cites W2094498491 @default.
• W2003620147 cites W2128179591 @default.
• W2003620147 cites W2139858161 @default.
• W2003620147 cites W2149459161 @default.
• W2003620147 cites W2569525354 @default.
• W2003620147 cites W2912671364 @default.
• W2003620147 cites W2949879428 @default.
• W2003620147 cites W2950265532 @default.
• W2003620147 cites W2950511243 @default.
• W2003620147 cites W2950564445 @default.
• W2003620147 cites W3004856319 @default.
• W2003620147 cites W3005465601 @default.
• W2003620147 cites W3137193840 @default.
• W2003620147 cites W3138481120 @default.
• W2003620147 cites W3153035729 @default.
• W2003620147 cites W347037257 @default.
• W2003620147 cites W4256034126 @default.
• W2003620147 cites W86000173 @default.
• W2003620147 cites W86748091 @default.
• W2003620147 doi "https://doi.org/10.1016/s0022-328x(03)00215-8" @default.
• W2003620147 hasPublicationYear "2003" @default.
• W2003620147 type Work @default.
• W2003620147 sameAs 2003620147 @default.
• W2003620147 citedByCount "13" @default.
• W2003620147 countsByYear W20036201472012 @default.
• W2003620147 countsByYear W20036201472016 @default.
• W2003620147 crossrefType "journal-article" @default.
• W2003620147 hasAuthorship W2003620147A5019355825 @default.
• W2003620147 hasAuthorship W2003620147A5041745355 @default.
• W2003620147 hasAuthorship W2003620147A5075891808 @default.
• W2003620147 hasAuthorship W2003620147A5081870737 @default.
• W2003620147 hasAuthorship W2003620147A5082532445 @default.
• W2003620147 hasAuthorship W2003620147A5091875084 @default.
• W2003620147 hasConcept C103319777 @default.
• W2003620147 hasConcept C116569031 @default.
• W2003620147 hasConcept C134121241 @default.
• W2003620147 hasConcept C155647269 @default.
• W2003620147 hasConcept C161790260 @default.
• W2003620147 hasConcept C163111631 @default.
• W2003620147 hasConcept C170493617 @default.
• W2003620147 hasConcept C178790620 @default.
• W2003620147 hasConcept C185592680 @default.
• W2003620147 hasConcept C188027245 @default.
• W2003620147 hasConcept C188328357 @default.
• W2003620147 hasConcept C191897082 @default.
• W2003620147 hasConcept C192562407 @default.
• W2003620147 hasConcept C2778689049 @default.
• W2003620147 hasConcept C2780400988 @default.
• W2003620147 hasConcept C2780471494 @default.
• W2003620147 hasConcept C2781349112 @default.
• W2003620147 hasConcept C40875361 @default.
• W2003620147 hasConcept C528581852 @default.
• W2003620147 hasConcept C544153396 @default.
• W2003620147 hasConcept C55493867 @default.

• next