Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003638963> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2003638963 endingPage "733" @default.
- W2003638963 startingPage "727" @default.
- W2003638963 abstract "The synthesis and characterisation of platinum(II) complexes, with the general formula [Pt(acylthioureato)Cl(RR′SO)], is reported. These complexes are readily formed by the reaction of [PtCl2(RR′SO)2] with the acylthiourea ligands, N,N-di(2-hydroxyethyl)-N′-benzoylthiourea (HL), N,N-diethyl-N′-benzoylthiourea (HL1) and N,N-adipoylbis(N′,N′-diethylthiourea) (H2L2) in the presence of sodium acetate. Variation of the sulfoxide ligand (RR′SO) enables preparation of achiral complexes when RR′SO is dimethylsulfoxide (DMSO) or methylphenylsulfoxide (MPSO), and chiral complexes when use is made of the chiral sulfoxides, such as (R)-methyl(p-tolyl)sulfoxide and (S)-methyl(p-tolyl)sulfoxide. The reaction also yields, as a minor product, the corresponding cis-bis(acylthioureato)platinum(II) complexes, which can be removed by chromatography. The molecular structures of the two products, [Pt(L1)Cl(MPSO)] and cis-[Pt(L1)2], were determined by X-ray crystallography. The sulfoxide of [Pt(L1)Cl(MPSO)] is sulfur bound, as expected, and cis to the sulfur atom of the acylthioureato ligand. All bond lengths and bond angles around the square planar platinum are normal, with the Pt–S bond trans to Cl being 2.257(4) Å and the Pt–S bond trans to O 2.192(3) Å in length. The Pt–O and Pt–Cl bonds are 2.016(9) and 2.334(3) Å, respectively, and are within the expected ranges. Similarly, the bond lengths and bond angles around the coordination plane of cis-[Pt(L1)2] compare well with related complexes." @default.
- W2003638963 created "2016-06-24" @default.
- W2003638963 creator A5009908424 @default.
- W2003638963 creator A5016488353 @default.
- W2003638963 creator A5041691385 @default.
- W2003638963 creator A5058113423 @default.
- W2003638963 date "2000-01-01" @default.
- W2003638963 modified "2023-09-23" @default.
- W2003638963 title "Chiral and achiral platinum(II) complexes for potential use as chemotherapeutic agents: crystal and molecular structures of cis-[Pt(L1)2] and [Pt(L1)Cl(MPSO)] [HL1 = N,N-diethyl-N ′-benzoylthiourea]" @default.
- W2003638963 cites W1966980421 @default.
- W2003638963 cites W1984566900 @default.
- W2003638963 cites W1985643236 @default.
- W2003638963 cites W1986204906 @default.
- W2003638963 cites W1999526688 @default.
- W2003638963 cites W2005841990 @default.
- W2003638963 cites W2007687417 @default.
- W2003638963 cites W2018122613 @default.
- W2003638963 cites W2030212940 @default.
- W2003638963 cites W2046433749 @default.
- W2003638963 cites W2050019289 @default.
- W2003638963 cites W2052241603 @default.
- W2003638963 cites W2056116492 @default.
- W2003638963 cites W2074418234 @default.
- W2003638963 cites W2088713484 @default.
- W2003638963 cites W2327551931 @default.
- W2003638963 doi "https://doi.org/10.1039/a908985c" @default.
- W2003638963 hasPublicationYear "2000" @default.
- W2003638963 type Work @default.
- W2003638963 sameAs 2003638963 @default.
- W2003638963 citedByCount "57" @default.
- W2003638963 countsByYear W20036389632012 @default.
- W2003638963 countsByYear W20036389632013 @default.
- W2003638963 countsByYear W20036389632014 @default.
- W2003638963 countsByYear W20036389632015 @default.
- W2003638963 countsByYear W20036389632017 @default.
- W2003638963 countsByYear W20036389632018 @default.
- W2003638963 countsByYear W20036389632019 @default.
- W2003638963 countsByYear W20036389632020 @default.
- W2003638963 countsByYear W20036389632021 @default.
- W2003638963 countsByYear W20036389632022 @default.
- W2003638963 countsByYear W20036389632023 @default.
- W2003638963 crossrefType "journal-article" @default.
- W2003638963 hasAuthorship W2003638963A5009908424 @default.
- W2003638963 hasAuthorship W2003638963A5016488353 @default.
- W2003638963 hasAuthorship W2003638963A5041691385 @default.
- W2003638963 hasAuthorship W2003638963A5058113423 @default.
- W2003638963 hasConcept C115624301 @default.
- W2003638963 hasConcept C116569031 @default.
- W2003638963 hasConcept C155647269 @default.
- W2003638963 hasConcept C155860418 @default.
- W2003638963 hasConcept C161790260 @default.
- W2003638963 hasConcept C170493617 @default.
- W2003638963 hasConcept C178790620 @default.
- W2003638963 hasConcept C185592680 @default.
- W2003638963 hasConcept C193547582 @default.
- W2003638963 hasConcept C2778448320 @default.
- W2003638963 hasConcept C32909587 @default.
- W2003638963 hasConcept C518104683 @default.
- W2003638963 hasConcept C55493867 @default.
- W2003638963 hasConcept C71240020 @default.
- W2003638963 hasConcept C8010536 @default.
- W2003638963 hasConceptScore W2003638963C115624301 @default.
- W2003638963 hasConceptScore W2003638963C116569031 @default.
- W2003638963 hasConceptScore W2003638963C155647269 @default.
- W2003638963 hasConceptScore W2003638963C155860418 @default.
- W2003638963 hasConceptScore W2003638963C161790260 @default.
- W2003638963 hasConceptScore W2003638963C170493617 @default.
- W2003638963 hasConceptScore W2003638963C178790620 @default.
- W2003638963 hasConceptScore W2003638963C185592680 @default.
- W2003638963 hasConceptScore W2003638963C193547582 @default.
- W2003638963 hasConceptScore W2003638963C2778448320 @default.
- W2003638963 hasConceptScore W2003638963C32909587 @default.
- W2003638963 hasConceptScore W2003638963C518104683 @default.
- W2003638963 hasConceptScore W2003638963C55493867 @default.
- W2003638963 hasConceptScore W2003638963C71240020 @default.
- W2003638963 hasConceptScore W2003638963C8010536 @default.
- W2003638963 hasIssue "5" @default.
- W2003638963 hasLocation W20036389631 @default.
- W2003638963 hasOpenAccess W2003638963 @default.
- W2003638963 hasPrimaryLocation W20036389631 @default.
- W2003638963 hasRelatedWork W1991736768 @default.
- W2003638963 hasRelatedWork W2014017601 @default.
- W2003638963 hasRelatedWork W2035567130 @default.
- W2003638963 hasRelatedWork W2051423384 @default.
- W2003638963 hasRelatedWork W2090170012 @default.
- W2003638963 hasRelatedWork W2330985842 @default.
- W2003638963 hasRelatedWork W2332841977 @default.
- W2003638963 hasRelatedWork W2386046626 @default.
- W2003638963 hasRelatedWork W2739936718 @default.
- W2003638963 hasRelatedWork W3140383084 @default.
- W2003638963 isParatext "false" @default.
- W2003638963 isRetracted "false" @default.
- W2003638963 magId "2003638963" @default.
- W2003638963 workType "article" @default.