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- W2003662911 abstract "The flow behaviour of a polyester in various solvents was studied at temperatures ranging from 10 to 80°C. The practical data obtained from the temperature dependence of limiting viscosity number [η] were used to calculate unperturbed dimensions and interaction parameters of the polyester resin in poor, moderate and good solvents. The data provided information regarding conformational transitions in the polymer chains in terms of exothermic or endothermic local ordering of solvents on resin segments and their fixation on polymer coils. The temperature dependence of unperturbed dimensions Ke, Flory–Huggins interaction parameter χ12, the second virial coefficient A2, entropy parameter U1, enthalpy parameter K1, and viscosity expansion factor αn, has been used to estimate the solvent quality for the resin." @default.
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- W2003662911 date "1994-07-01" @default.
- W2003662911 modified "2023-09-22" @default.
- W2003662911 title "Temperature dependence of unperturbed dimension and interaction parameters of polyester resin in solvents" @default.
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- W2003662911 doi "https://doi.org/10.1002/pi.1994.210340304" @default.
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