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- W2003677424 abstract "The adsorption of CO and benzene on pseudomorphic Cu monolayers on Ni(1 1 1) and Ru(0 0 0 1) shows pronounced differences: For Cu/Ni(1 1 1) a behavior very similar to that of Cu(1 1 1) is observed, for Cu/Ru(0 0 0 1) the adsorbate substrate bond is significantly strengthened for both molecules, as is deduced from a shift of the desorption temperature to higher values. Based on angle resolved UV photoelectron spectroscopy using synchrotron radiation at BESSY and density functional calculations we have determined the two-dimensional band structure of the pseudomorphic Cu monolayers on Ni(1 1 1) and Ru(0 0 0 1). Our results show that for Cu/Ni(1 1 1) only weak coupling of the Cu 3d states to the Ni substrate states occurs. On the other hand, strong coupling is observed for Cu/Ru(0 0 0 1). This difference is made responsible for the strongly modified chemical properties of Cu/Ru(0 0 0 1) as compared to Cu/Ni(1 1 1)." @default.
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- W2003677424 date "2001-04-01" @default.
- W2003677424 modified "2023-10-18" @default.
- W2003677424 title "Correlation between chemical properties and electronic structure of pseudomorphic Cu monolayers on Ni(111) and Ru(0001)" @default.
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- W2003677424 doi "https://doi.org/10.1016/s0039-6028(01)00889-5" @default.
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