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• W2003703729 abstract "A series of asymmetrically substituted dodecafluorinated phthalocyanines has been synthesized via the Kobayashi ring expansion reaction of the corresponding dodecafluorinated boron subphthalocyanine with differently substituted 1,3-diiminoisoindolines. The mild reaction conditions employed during this ring expansion reaction gave rise exclusively to 3:1 asymmetrically substituted dodecafluorinated phthalocyanines. Metal insertion into the metal-free phthalocyanines was accomplished by heating at 40 degrees C in N,N-dimethylformamide in the presence of zinc bromide. The resulting zinc dodecafluorophthalocyanines were formulated as Cremophor EL oil-water emulsions and evaluated as photosensitizers in vitro against EMT-6 mouse mammary tumor cells. As compared to the previously studied zinc hexadecafluorophthalocyanine, these new asymmetrical zinc dodecafluorophthalocyanines exhibited improved photodynamic activity." @default.
• W2003703729 created "2016-06-24" @default.
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• W2003703729 date "2005-09-01" @default.
• W2003703729 modified "2023-10-16" @default.
• W2003703729 title "Synthesis and Photodynamic Activity of Novel Asymmetrically Substituted Fluorinated Phthalocyanines" @default.
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• W2003703729 doi "https://doi.org/10.1021/bc0500241" @default.
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