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- W2003711253 abstract "Abstract Spectrophotometric measurements of aqueous solutions containing nickel(II) and pyrazine at pH 4, μ = 1·0 M, have yielded for the 1:1 complex the formation quotient Kf = 10·3 ± 0·6 M−1 at 25°C with ΔH and ΔS equal to −3·2 ± 0·5 kcal/mole and −6 ± 2 cal. deg−1 mole−1, respectively. Temperature-jump relaxation measurements gave for the forward and reverse specific rate constants, respectively, 2·8 ± 0·1 × 103M−1 sec−1 and 3·5 ± 0·5 × 102 sec−1 at 19·5°C." @default.
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- W2003711253 date "1972-10-01" @default.
- W2003711253 modified "2023-10-16" @default.
- W2003711253 title "The aqueous pyrazine-nickel(II) complex" @default.
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- W2003711253 doi "https://doi.org/10.1016/0022-1902(72)80118-0" @default.
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