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- W2003721190 abstract "ABSTRACT Octyl and dodecyl fucosides were synthesized by the tin tetrachloride catalyzed reaction of fucose tetraacetate 7 and the corresponding alcohol. Separation of the reaction mixture afforded pyranosides and furanosides. The liquid crystalline properties of compounds 6, 11 and 14 were determined, and for the last a new phase is observed and discussed. Beyond the classical rules for liquid crystalline behavior, molecular principles which serve as a basis for a broader interpretation of all different mesophases are proposed. The synthesized derivatives are considered to represent a novel organisational type of liquid crystalline compounds, for which the concept “monolayer with frustrated chain end” is suggested." @default.
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- W2003721190 date "1991-01-01" @default.
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- W2003721190 title "Liquid Crystalline 6-Deoxy Glycosides" @default.
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