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- W2003766393 abstract "We observed that the poly(p-phenylenevinylene) units in Langmuir monolayers of partly converted dimethoxy-substituted poly(p-phenylenevinylene) precursor polymers oxidize at the air−water interface. This reaction even happened in the dark and therefore can not be attributed to a photooxygenation reaction with singlet oxygen. We assume that ground-state triplet oxygen is polarized at the air−water interface and forms a weakly bound complex with the double bond to give a reactive intermediate state, which lowers the activation energy of the oxidation reaction. The air−water interface thus works as a catalyst in this reaction." @default.
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- W2003766393 date "2000-05-01" @default.
- W2003766393 modified "2023-10-16" @default.
- W2003766393 title "Oxidation of Monolayers of Partly Converted Dimethoxy-Substituted Poly(p-phenylenevinylene) Precursor Polymers at the Air−Water Interface" @default.
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- W2003766393 doi "https://doi.org/10.1021/la9914209" @default.
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