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- W2003773417 abstract "ABSTRACT The polymerization of acrylamide in micellar solutions of cationic, anionic, zwitterionic and nonionic surfactants, initiated by NaHSO3, has been studied at 20 and 30° C with time variable method of thermokinetics for the 1. 5-order reaction in this paper. Reaction mechanism has been suggested and rate equations have been derived. The results indicate that ionic (CTAB, TTABDTAB, SDS) and zwitterionic (SLS) surfactants catalyze the polymerization in the order SDS>SLS>DTAB ≈ TTA≈ CTAB, and nonionic surfactant (Brij35) has slight inhibition effect. These effects are mainly caused by the effect of the formation of micelle- HSO3 complex on the step of initiator to form free radical." @default.
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- W2003773417 date "1999-06-01" @default.
- W2003773417 modified "2023-09-26" @default.
- W2003773417 title "THE EFFECT OF SINGLE MICELLES OF SURFACTANTS ON POLYMERIZATION OF ACRYLAMIDE" @default.
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- W2003773417 doi "https://doi.org/10.1080/01932699908943849" @default.
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