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• W2003808782 abstract "Incoming molecular hydrogen breaks the RuS bridges in the diruthenium complex [Ru(pybuS4)]2 (pybuS42−=2,6-bis(2-sulfanyl-3,5-di-tert-butylphenylthio)dimethylpyridine(2−)) shown, and the HH bond is cleaved to give H+ and H− in the resulting thiol-protonated hydride [Ru(H)(pybuS4-H)]. The proposed mechanism of the heterolytic cleavage of H2 at the RuS centers is intriguing and possibly relevant to the activation of H2 by hydrogenases." @default.
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• W2003808782 date "2004-03-24" @default.
• W2003808782 modified "2023-10-18" @default.
• W2003808782 title "Heterolytic Cleavage of H2 at a Sulfur-Bridged Dinuclear Ruthenium Center" @default.
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• W2003808782 doi "https://doi.org/10.1002/anie.200453717" @default.
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