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- W2003811516 abstract "Trivalent lanthanide and actinide complexes of the types M(dtc)3 and NEt4M(dtc)4(M = Np, Pu, and La to Lu inclusive, except Pm; dtc =NN-diethyldithiocarbamate) have been prepared by reactions in nonaqueous solvents. Some chemical properties, i.r. and visible spectra, and crystallographic properties are reported. Three distinct crystal forms have been observed for different neutral complexes whereas the tetrakisdiethyldithiocarbamates are all isostructural. The structure of NEt4Np(dtc)4 has been determined by single-crystal X-ray diffraction methods. It crystallises in the monoclinic space group P21/c(C2h5) with Z= 4 in a unit cell of dimensions a0= 11·68, b0= 20·49, c0= 19·14 Å and β= 116·5°. The neptunium atoms are each bonded to eight sulphur atoms with a mean Np–S distance of 2·87 Å." @default.
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- W2003811516 date "1970-01-01" @default.
- W2003811516 modified "2023-09-25" @default.
- W2003811516 title "NN-diethyldithiocarbamate complexes of trivalent lanthanide and actinide elements and the crystal structure of tetraethylammonium neptunium(III) tetrakis-(NN-diethyldithiocarbamate)" @default.
- W2003811516 doi "https://doi.org/10.1039/j19700000786" @default.
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