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- W2003816613 abstract "The effect of support (kieselguhr) and promoter (ThO2) in Fischer-Tropsch cobalt catalysts has been investigated using H2 and CO adsorption, X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction (TPR) techniques. The extent of reduction is found to be 39% in the presence of kieselguhr due to its migration to the surface of cobalt oxide. Presence of ThO2 increases the extent of reduction to 75% probably restricting the migration of kieselguhr. XPS results show the preferential segregation of ThO2 on the surface thus preventing the encapsulation of cobalt oxide by kieselguhr. The CO/Co and H/Co values decrease with decrease in cobalt loadings indicating the possible interaction between cobalt and kieselguhr. During reduction, kieselguhr is found to stabilize CoO as revealed from TPR studies." @default.
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- W2003816613 title "Effect of support and promoter in Fischer-Tropsch cobalt catalysts" @default.
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- W2003816613 doi "https://doi.org/10.1016/0021-9517(86)90359-3" @default.
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