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- W2003838218 abstract "(C6H5)6Sn2 kristallisiert in der monoklinen Raumgruppe P21/c(C) mit a = 17,338(3), b = 9,379(2), c = 21,472(3) Å, β = 117,33(9)° und Z = 4. Die Kristall- und Molekularstruktur wurde anhand von 2939 unabhängigen Reflexen mittels Fourier-Synthesen bestimmt und mit Least-Squares-Methoden dreidimensional verfeinert. Die Elementarzelle enthält zwei kristallographisch unabhängige Molekeln der Punkt-symmetrie S6. Die Mittelwerte der Bindungsabstände bzw. Bindungswinkel betragen Sn Sn = 2,770(4), SnC = 2,180(16), C C = 1,39(3) Å; Sn Sn C = 110,25(51)°, C Sn C = 108,67(63)°. (C6H5)Sn2 ist isomorph mit (C6H5)6Pb2, nicht jedoch mit (C6H5)6Ge2, welches hexagonal kristallisiert (a = 17,427(5), c = 8,484(3) Å). Crystal and Molecular Structure of Hexaphenyl Distannane (C6H5)6Sn2 crystallizes in the monoclinic space group P21/c(C) (lattice parameters see above). The crystal and molecular structure has been determined from 2939 independent reflexes by FOURIER analyses and refined three dimensionally by least- squares-methods. The unit cell contains two crystallographically independent molecules of symmetry S6. (Mean values of bond lengths and bond angles see above). (C6H5)6Sn2 is isomorphous with (C6H5)6Pb2, but not with (C6H5)6Gc2, which crystallizes hexagonally (lattice parameters see above)." @default.
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- W2003838218 date "1973-01-01" @default.
- W2003838218 modified "2023-10-17" @default.
- W2003838218 title "Die Kristall-und Molekularstruktur des Hexaphenyl-distannans" @default.
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- W2003838218 doi "https://doi.org/10.1002/zaac.19733960109" @default.
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