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- W2003883428 abstract "Methanol and carbon monoxide oxidation were examined over 0.01 Pd, 5% Ag, and 0.01% Pd/5% Ag catalysts—all supported on γ-alumina. The bimetallic catalyst showed greater CO and CH3OH oxidation activity than either of the single-component catalysts; moreover, the Pd and Ag interacted synergistically in the bimetallic catalyst to produce greater CO and CH3OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. Temperature-programmed oxidation experiments and reactivity experiments involving changes in O2 partial pressure both provided evidence that the PdAg synergism results from Pd promoting the rate of O2 adsorption and reaction with CO and CH3OH on Ag. The data also indicate that virtually all of the Pd in the bimetallic catalyst is present in Pd-Ag crystallites." @default.
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- W2003883428 date "1987-02-01" @default.
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- W2003883428 title "Exhaust-catalyst development for methanol-fueled vehicles 2. Synergism between palladium and silver in methanol and carbon monoxide oxidation over an alumina-supported palladium-silver catalyst" @default.
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- W2003883428 doi "https://doi.org/10.1016/0021-9517(87)90133-3" @default.
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