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- W2003886124 abstract "The highly regioselective cobalt-catalysed 1,4-hydrovinylation of terminal alkenes with 2-trimethylsilyloxy-1,3-butadiene generates in a stereospecific fashion unsaturated E-configured silyl enol ether intermediates that are suitable for diastereoselective Mukaiyama-aldol reactions with bulky aliphatic aldehydes. The acidic hydrolysis of the enol ethers to γ,δ-unsaturated ketones followed by ozonolysis can be used for the synthesis of various 1,4-diketones and polycarbonyl derivatives. The 1,4-diketones and polycarbonyl derivatives were successfully tested for the synthesis of some mono- and bis-pyrrole derivatives. The γ,δ-unsaturated ketones are useful building blocks (e.g., in natural product synthesis) and can be generated in a one-pot procedure." @default.
- W2003886124 created "2016-06-24" @default.
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- W2003886124 date "2012-02-28" @default.
- W2003886124 modified "2023-09-30" @default.
- W2003886124 title "Regioselective Cobalt-Catalysed Hydrovinylation for the Synthesis of Non-Conjugated Enones and 1,4-Diketones" @default.
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- W2003886124 doi "https://doi.org/10.1002/adsc.201100800" @default.
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